张学海, 魏合理, 段金龙, 李卫东, 邹曙光, 戴聪明. 灰霾期间硫酸盐包裹沙尘气溶胶粒子的光学特性研究[J]. 红外与激光工程, 2021, 50(11): 20210052. DOI: 10.3788/IRLA20210052
引用本文: 张学海, 魏合理, 段金龙, 李卫东, 邹曙光, 戴聪明. 灰霾期间硫酸盐包裹沙尘气溶胶粒子的光学特性研究[J]. 红外与激光工程, 2021, 50(11): 20210052. DOI: 10.3788/IRLA20210052
Zhang Xuehai, Wei Heli, Duan Jinlong, Li Weidong, Zou Shuguang, Dai Congming. Study on the optical properties of sulfate coated dust aerosol particles during haze episodes[J]. Infrared and Laser Engineering, 2021, 50(11): 20210052. DOI: 10.3788/IRLA20210052
Citation: Zhang Xuehai, Wei Heli, Duan Jinlong, Li Weidong, Zou Shuguang, Dai Congming. Study on the optical properties of sulfate coated dust aerosol particles during haze episodes[J]. Infrared and Laser Engineering, 2021, 50(11): 20210052. DOI: 10.3788/IRLA20210052

灰霾期间硫酸盐包裹沙尘气溶胶粒子的光学特性研究

Study on the optical properties of sulfate coated dust aerosol particles during haze episodes

  • 摘要: 灰霾期间硫酸盐与沙尘矿物颗粒表面经过系列化学反应形成复杂的混合状态,为气溶胶光学性质模拟带来很大困难。因此,厘清硫酸盐壳对沙尘矿物颗粒光学特性的影响机制具有重要意义。文中根据灰霾期间硫酸盐与沙尘矿物颗粒反应过程中的混合结构变化,建立了沙尘-硫酸盐颗粒的核壳椭球结构模型。采用T矩阵方法,研究了四波段条件(0.44、0.675、0.87、1.02 μm)下,混合比对单分散系沙尘-硫酸盐粒子光学特性的影响。结果表明:混合比对沙尘-硫酸盐粒子光学特性的影响主要在Mie散射区,在瑞利散射区,混合比对粒子光学特性影响不大。同时研究结果还表明,当混合比小于0.3时,硫酸盐壳在粒子散射特性中占主导地位;当混合比大于0.7时,粒子散射特性主要受沙尘核的影响;在此区间内,粒子散射特性由硫酸盐与沙尘共同影响,并会出现强于(或弱于)任何一种纯颗粒物的现象。该研究对理解灰霾老化期间单颗粒气溶胶混合结构及其光学特性具有重要意义。

     

    Abstract: The complex mixing state of sulfate and mineral dust particles is formed through a series of chemical reactions, which bring great difficulties to understand the optical properties of atmosphere aerosols during haze episodes. Therefore, it is of great significance to clarify the influence mechanism of sulfate core on the optical properties of mineral dust particles. In this paper, a "core-shell" ellipsoidal structure model of dust and sulfate (D-S) aerosols was established based on the actual haze conditions according to mixing structure change in the action process between sulfate and mineral dust particles. The influence of mixing ratio on the optical properties of monodisperse dust-sulfate particles at four selected wavelength (0.44, 0.675, 0.87 and 1.02 μm) was studied by using the T-matrix method. The results show that the influence of mixing ratio on the optical properties of D-S particles is mainly in the Mie scattering region, while the effect of mixing ratio is not obvious in the Rayleigh scattering region. When the mixing ratio is less than 0.3, the sulfate shell plays a dominant role in the particle scattering characteristics, while the mixing ratio is greater than 0.7, the particle scattering characteristics are mainly affected by the dust core. In the range of 0.3-0.7, the scattering characteristics are influenced by D-S, and maybe stronger or weaker than any kind of pure particles. The research is of great significance to understand the mixing structure and optical properties of individual aerosol particles during haze aging process.

     

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