Volume 48 Issue 11
Dec.  2019
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Cheng Haijuan, Yu Xiaohui, Peng Lang, Pu Qunyan, Cai Yi, Li Maozhong, Yang Weisheng, Bai Yuzhuo, Zhao Jinsong, Wang Lingxue. LaF3-ZnS-Ge high-durability MWIR antireflective film on Ge substrate[J]. Infrared and Laser Engineering, 2019, 48(11): 1117001-1117001(7). doi: 10.3788/IRLA201948.1117001
Citation: Cheng Haijuan, Yu Xiaohui, Peng Lang, Pu Qunyan, Cai Yi, Li Maozhong, Yang Weisheng, Bai Yuzhuo, Zhao Jinsong, Wang Lingxue. LaF3-ZnS-Ge high-durability MWIR antireflective film on Ge substrate[J]. Infrared and Laser Engineering, 2019, 48(11): 1117001-1117001(7). doi: 10.3788/IRLA201948.1117001

LaF3-ZnS-Ge high-durability MWIR antireflective film on Ge substrate

doi: 10.3788/IRLA201948.1117001
  • Received Date: 2019-09-11
  • Rev Recd Date: 2019-10-21
  • Publish Date: 2019-11-25
  • Evaporation characteristics and optical constants of LaF3 materials in 2.5-12 m infrared band were investigated. With low refractive index LaF3 materials, high-durability antireflection (AR) coatings in 3.7-4.8 m medium-wavelength infrared bands were designed and fabricated on Ge substrate. SEM image of the AR coatings with the LaF3 shows that the surface nanocrystals is uniform and densified. The measured optical properties by Fourier tranform infrared spectrometer indicate that the peak transmittance is as high as 99.4%, and the average transmittance increases to 98.8% from 47.7% in 3.7-4.8 m after double-sided coating. The firmness and durability environmental tests signify that this AR coating can work in harsh environment while maintaining good optical properties.
  • [1] Meenakshi B, Nautiyal B B, Bandyopadhyay P K. High efficiency antireflection coating in MWIR region (3.6-4.9m) simultaneously effective for Germanium and Silicon optics.[J]. Infrared Physics Technology, 2010, 53(1):33-36.
    [2] Behranvanda A, Davoudi Darareha M, Jannesaria M, et al. Design and fabrication of PbTe/BaF2 hydrophobic high-efficiency broa dband antireflection coating on Ge substrate in long-wave infrared region[J]. Infrared Physics and Technology, 2018, 92:163-165.
    [3] Gainutdinov I S, Yu N, Shuvalov R S, et al. Antireflection coatings on germanium and silicon substrates in the 3-5m and 8-12m windows of IR transparency[J]. Journal of Optical Technology, 2009, 76(5):302-305.
    [4] Yan Lanqin, Zhang Shuyu, Liu Wei, et al. High performance infrared wide-band (7.5-11.5m) anti-reflective film on germanium substrate[J]. Infrared and Laser Engineering, 2010, 39(5):871-874. (in Chinese)
    [5] Zhang Dawei, Huang Yuanshen, He Hongbo, et al. Antireflective film prepared by periodic ion beam assisted deposition[J]. Optics and Precision Engineering, 2007, 15(10):1463-1468. (in Chinese)
    [6] Fu Xiuhua, Yang Jinye, Liu Dongmei, et al. Design and preparation of anti-reflection and protective film in 8-11m infrafed detection system[J]. Infrared and Laser Engineering, 2014, 43(12):3889-3893. (in Chinese)
    [7] Lu Yimin, Huang Guojun, Guo Yanlong, et al. Experiment research on the double-layer diamond-like carbon film prepared by double laser beams[J]. Infrared and Laser Engineering, 2018, 47(11):1121003. (in Chinese)
    [8] Sun P, Hu M, Zhang F, et al. The infrared optical and mechanical properties of germanium carbide films prepared by ion beam sputtering[J]. Journal of Infrared Millimeter Waves, 2016, 35(2):133-138.
    [9] Liu W, Tu H, Gao M, et al. High performance DLC/BP and ZnS/YbF3 double-layer protective and antireflective coatings[J]. Journal of Alloys and Compounds, 2013, 581:526-569.
    [10] Li Y P, Wang N, Che X S, et al. Infrared transmissive and rain-erosion resistant performances of GeC/GaP double-layer thin films on ZnS substrates[J]. Appl Surf Sci, 2013, 264:538-544.
    [11] Li Chun, Jin Chunshui, Jin Jingcheng, et al. Realization of antireflection coatings for 193 nm P-polarized light at large angle[J]. Chinese Journal of Lasers, 2013, 40(9):0907001. (in Chinese)
    [12] Won Tae, Seoung Jae I M, Jeon Geon H, et al. LaF3/MgO protective layer in AC-plasma display panels[J].Japanese Journal of Applied Physics, 2003, 42(7A):4501-4503.
    [13] Li Bin, Xie Ping, Su Weitao, et al. Combinatorial synthesis of BaClF-ReF3(Re=La, Pr, Er, Sm) layers with graded-index as antireflection coatings in the thermal infrared[J]. Materials Design, 2016, 107:302-310.
    [14] Tang Jinfa, Gu Peifu, Liu Xue, et al. Modern Optical Thin Film Technology[M]. Hangzhou:Zhejiang Uuiversity Press, 2006:240-240. (in Chinese)
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LaF3-ZnS-Ge high-durability MWIR antireflective film on Ge substrate

doi: 10.3788/IRLA201948.1117001
  • 1. School of Optics and Photonics,Beijing Institute of Technology,Beijing 100081,China;
  • 2. North Night-Vision Science& Technology Group Co.,Ltd,Kunming 650221,China

Abstract: Evaporation characteristics and optical constants of LaF3 materials in 2.5-12 m infrared band were investigated. With low refractive index LaF3 materials, high-durability antireflection (AR) coatings in 3.7-4.8 m medium-wavelength infrared bands were designed and fabricated on Ge substrate. SEM image of the AR coatings with the LaF3 shows that the surface nanocrystals is uniform and densified. The measured optical properties by Fourier tranform infrared spectrometer indicate that the peak transmittance is as high as 99.4%, and the average transmittance increases to 98.8% from 47.7% in 3.7-4.8 m after double-sided coating. The firmness and durability environmental tests signify that this AR coating can work in harsh environment while maintaining good optical properties.

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