朱卓亚, 张帅, 杜文娜, 张青, 刘新风. 基于卤化物钙钛矿的法布里-珀罗微腔中激子极化激元(特邀)[J]. 红外与激光工程, 2021, 50(11): 20210619. DOI: 10.3788/IRLA20210619
引用本文: 朱卓亚, 张帅, 杜文娜, 张青, 刘新风. 基于卤化物钙钛矿的法布里-珀罗微腔中激子极化激元(特邀)[J]. 红外与激光工程, 2021, 50(11): 20210619. DOI: 10.3788/IRLA20210619
Zhu Zhuoya, Zhang Shuai, Du Wenna, Zhang Qing, Liu Xinfeng. Exciton-polaritons in Fabry-Pérot microcavity based on halide perovskites (Invited)[J]. Infrared and Laser Engineering, 2021, 50(11): 20210619. DOI: 10.3788/IRLA20210619
Citation: Zhu Zhuoya, Zhang Shuai, Du Wenna, Zhang Qing, Liu Xinfeng. Exciton-polaritons in Fabry-Pérot microcavity based on halide perovskites (Invited)[J]. Infrared and Laser Engineering, 2021, 50(11): 20210619. DOI: 10.3788/IRLA20210619

基于卤化物钙钛矿的法布里-珀罗微腔中激子极化激元(特邀)

Exciton-polaritons in Fabry-Pérot microcavity based on halide perovskites (Invited)

  • 摘要: 当激子与腔光子间的相互作用强于激子和腔光子的衰减时,激子能级与腔模之间产生强耦合,形成的准粒子被称为激子极化激元。激子极化激元有效质量小,同时具有较强的非线性,在慢光和低功耗发光器件等方面具有巨大的应用前景。传统Ⅲ-Ⅴ族无机半导体材料激子束缚能较弱,而有机半导体材料非线性系数较小等问题限制着室温条件下激子极化激元的应用。卤化物钙钛矿材料具有高吸收系数、长扩散长度、高缺陷容忍度以及低非辐射复合率等一系列优异的光电性质,并且具有高的激子束缚能和振子强度,成为研究光与物质强相互作用的理想材料。文中从卤化物钙钛矿结构和法布里-珀罗(Fabry-Pérot, F-P)微腔类型两方面介绍了近年来卤化物钙钛矿与F-P微腔强耦合在激子极化激元方面的研究进展。首先回顾了极化激元的研究背景和卤化物钙钛矿的基本光电特性,其次介绍了三维钙钛矿和二维层状钙钛矿各自的特点以及与F-P微腔强耦合的相关研究,随后对钙钛矿的自构型和非自构型F-P微腔激子极化激元的调控与相关应用进行了讨论,最后总结和展望了卤化物钙钛矿激子极化激元面临的挑战以及未来研究方向。

     

    Abstract: When the interaction between excitons and cavity photons is stronger than the decay of excitons and cavity photons, a strong coupling occurs between exciton energy level and cavity mode, thereby generating the quasi-particles called exciton-polaritons. The small effective mass and strong nonlinearity of exciton-polariton make it great potential in the applications of slow light and low-power-consumption light emission devices. However, weak exciton binding energy of traditional III-V inorganic semiconductor materials and weak nonlinearity of organic semiconductor materials limit their application of exciton-polaritons at room temperature. In contrast, halide perovskites have a series of excellent photoelectric properties such as high absorption coefficient, long diffusion length, high defect tolerance, and low rates of nonradiative recombination. Furthermore, with large exciton binding energy and oscillator strength, halide perovskites become an ideal material for studying strong interaction between light and matter. The research progress on exciton-polaritons based on the strong coupling between halide perovskite and Fabry-Pérot (F-P) microcavities was introduced from two aspects: the structure kinds of halide perovskites and the type of F-P microcavities. Firstly, the research background of polaritons and the basic photoelectric properties of halide perovskites were reviewed. Secondly, the respective characteristics of three-dimensional perovskites and two-dimensional layered perovskites and related research on strong coupling with F-P microcavities were introduced. Afterwards, the regulation and application of self-organized and non-self-organized F-P microcavities to perovskite exciton-polaritons were discussed. Finally, the challenges and future research directions of halide perovskite exciton-polaritons were summarized and prospected.

     

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