基于硫系玻璃-聚甲基丙烯酸甲酯分光结构的散斑计算重组光谱仪设计

Design of speckle calculation recombination spectrometer based on chalcogenide glass-polymethyl methacrylate spectroscopic structure

  • 摘要: 传统的台式光谱仪多采用大体积、长光程的色散分光方式,往往只能在实验室使用。而手持式光谱仪多采用可调光学滤波器或傅里叶变换的方法,内部存在精密的移动部件,制造难度大。使用硫系玻璃IG2和聚甲基丙烯酸甲酯(PMMA)材料,研究了这两种材料的均匀随机分布方法,以两种材料折射率变化的差异为基础构筑了无序散射结构,结合散斑计算重组的方法设计了一种量程和分辨率可变的小型红外光谱仪系统,结构简单、稳定,无移动部件,可通过不同波长的标定光来确定该系统的量程和分辨率。利用Tracepro软件,采用不同的光源输入进行了标定,用模拟的黑体辐射作为测试输入,光谱仪系统在1~10.9 μm光谱范围内能够实现0.1 μm分辨率,在1000~2000 nm光谱范围内能够实现10 nm分辨率。采用六阶多项式对测量结果进行了拟合,拟合曲线的最大相对误差为5.32%,可满足煤矿、食品、药物等多方面的应用。

     

    Abstract:
      Objective  After nearly half a century of development, infrared spectroscopy has been widely used in food, medicine, biological diagnosis, agriculture, textile, oil refining and chemical industries. The optical path of the traditional infrared spectrometer is more complex, and often with moving parts, so the requirement of machining accuracy is very high, and the optical components in the optical path are also expensive. These factors make the infrared spectrometer expensive and the stability, reliability and working environment adaptability of the system weak. Small spectrometers have received extensive attention and developed rapidly due to their significant advantages in size, weight, and power consumption. In particular, computational spectral analysis technology based on speckle detection can obtain high-precision spectral information by recording and analyzing the speckle patterns formed by scattering elements on the measured light. Speckle computational reconstruction spectrometer has the advantages of both small size and high resolution, and because the preparation of scatterers is simpler and costs less than various strictly designed micro-nano structures or materials with different components, it is a spectral analysis technology with great application potential.
      Methods  A set of speckle calculation recombination spectrometer system is designed in this paper. The spectroscopic structure was designed using chalcogenide glass IG2 and polymethyl methacrylate (PMMA) materials. The uniform random distribution method of these two materials was studied. The disordered scattering structure was constructed based on the difference in refractive index changes of the two materials (Fig.3). The spectrometer system was tested by Tracepro software design simulation experiment.
      Results and Discussions  The speckle calculation recombination spectrometer system adopts a special spectroscopic structure. The spectroscopic structure is designed based on the uniform random distribution of chalcogenide glass IG2 and polymethyl methacrylate (PMMA), which can generate speckles with uniform distribution and high contrast, and has good spectroscopic effect (Fig.6). Multiple sets of simulation experiments were designed by Tracepro software to verify the performance of the system. In the 1-10.9 μm wavelength range, the relative error of the simulation results of the test light composed of the calibration light is 1.29% (Fig.7). The relative error of the simulation results of the uncalibrated 5.01 μm wavelength monochromatic light is 3.37% (Fig.8). The simulation results of uncalibrated 3 000 K blackbody radiation are fitted by 6-order polynomial. The maximum absolute error of the calculated value is 2.581 6 W, and the maximum absolute error of the fitting curve is 0.678 7 W (Fig.9). In the high-resolution simulation of 1-2 μm wavelength range, the simulation results of 3 000 K, 4 000 K and 5 000 K blackbody radiation are fitted by 6-order polynomial. The maximum relative errors of the fitting curves are 2.07%, 5.32% and 4.28%, respectively (Fig.10). The results of the simulation test show that the system can maintain small error under the condition of wide range or high resolution.
      Conclusions  A speckle calculation recombination spectrometer system with working wavelengths of 1-10 μm and 1 000-2 000 nm was designed. The system is characterized by small size, no moving components, simple and stable structure, low production cost and easy production. The system function was simulated by using Tracepro software. The resolution reached 0.1 μm in the spectral range of 1-10.9 μm, and the maximum relative error of the test results was 3.77%. The resolution reaches 10 nm in the spectral range of 1 000-2 000 nm, and the maximum relative error of the test results is 5.32%. The simulation results show that the system has large range, high resolution and low error, and can select the corresponding wavelength range according to the actual situation to meet different application requirements.

     

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